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Beilstein J. Org. Chem. 2016, 12, 1476–1486, doi:10.3762/bjoc.12.144
Graphical Abstract
Figure 1: Previous (UA1776, UA2201 and UA2209 [7,8]) and new 1a–q phosphonate derivatives designed as potential cN...
Scheme 1: Synthesis of (1-azido-2,5-di-O-acetyl-3-O-benzoyl-6-deoxy-6-diethylphosphono)-β-ribo-(5S)-hexofuran...
Scheme 2: General synthetic pathway for the 1,2,3-triazolo-β-hydroxyphosphonate derivatives.
Figure 2: Black arrow indicates 1H,1H-COSY correlations for compound 2. Green (C1’ and H5) and blue (H1’ and ...
Figure 3: Arrows indicate 1H,1H-NOESY (blue) and 1H,13C-HMBC (green) correlations for compound 3h.
Figure 4: Arrows indicate 1H,1H-NOESY (blue) and 1H,13C-HMBC (green) correlations for compound 3i.
Figure 5: Inhibition of the nucleotidase activity in presence of representative triazole-based derivatives.
Figure 6: Comparison of the docking poses obtained for two active derivatives in the substrate binding site o...
Figure 7: Superimposition of the docking poses obtained for IMP (pink sticks), derivatives 1n (cyan sticks) a...
Figure 8: Comparison of the docking poses obtained for three active derivatives in the substrate binding site...